Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

Autor:	Drahomír Hnyk, Mario Bakardjiev, Aleš Růžička, Bohumil Štíbr, Jindřich Fanfrlík, Josef Holub, Zdeňka Růžičková, Oleg L. Tok, Zbyněk Špalt
Rok vydání:	2018
Předmět:	Inorganic Chemistry 010405 organic chemistry Stereochemistry Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Vertex (geometry)
Zdroj:	Dalton Transactions. 47:11070-11076
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c8dt02586j
Popis:	Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta – decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.
Databáze:	OpenAIRE
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