ChemInform Abstract: Regioselective Acylation of (5-Alkylidene-1,3-cyclohexadiene)tricarbonyliron Complexes by the Reaction with Organometallic Reagents

Autor:	Mitsuhiko Iwakoshi, Soo Ho Ban, Yujiro Hayashi, Koichi Narasaka
Rok vydání:	2010
Předmět:	Acylation chemistry.chemical_compound chemistry Reagent Regioselectivity Trimethylamine Moiety General Medicine 1 3-Cyclohexadiene Medicinal chemistry Acyl group Carbon monoxide
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199840083
Popis:	Reaction of [(1,2,3,4-η)-5-alkylidene-1,3-cyclohexadiene]tricarbonylirons and organometallic reagents generates acyl[(1,2,3,4,5-η)-1-alkylcyclohexadienyl]dicarbonylirons. The acyl group in these complexes migrates to the cyclohexadienyl moiety under carbon monoxide atmosphere, providing [(1,2,3,4-η)-6-acyl-2-alkyl-1,3-cyclohexadiene]tricarbonylirons, which are further transformed to m-alkylphenyl ketones by the oxidation with trimethylamine N-oxide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6ff6f0a48d570764fdc2f21b37fcbdc9 https://doi.org/10.1002/chin.199840083 Zobrazit plný text záznamu Plný text