High-resolution spectroscopy and analysis of the ν4 band of 80SeF6

Autor:	Hans Bürger, H. Willner, Maud Rotger, Vincent Boudon
Rok vydání:	2001
Předmět:	symbols.namesake Fourth order Chemistry symbols General Physics and Astronomy Infrared spectroscopy Mineralogy High resolution Physical and Theoretical Chemistry Atomic physics Spectroscopy Hamiltonian (quantum mechanics)
Zdroj:	Chemical Physics Letters. 339:83-88
ISSN:	0009-2614
Popis:	The Fourier-transform spectrum of the ν4 bending region of 80 SeF 6 around 435 cm −1 has been recorded at a temperature of 217 K with a resolution of 2.3×10 −3 cm −1 . This fundamental has been analyzed using the set of programs called highly spherical top data system (HTDS). Altogether 958 transitions were assigned and fitted with an rms of 0.0003 cm −1 . The effective Hamiltonian was developed up to the fourth order. Parameters and simulations are presented. The ν4 band center is located at 435.099 cm −1 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6fc6cafc4915648c6ceacfbb88170340 https://doi.org/10.1016/s0009-2614(01)00299-8 Zobrazit plný text záznamu Full Text from ScienceDirect