Chalcogen Diimides: Relative Stabilities of Monomeric and Dimeric Structures, [E(NMe)2]n (E = S, Se, Te; n = 1, 2)

Autor:	Tom Ziegler, Tristram Chivers, Nicole Sandblom
Rok vydání:	1998
Předmět:	Steric effects chemistry.chemical_element Antibonding molecular orbital Endothermic process Sulfur Inorganic Chemistry chemistry.chemical_compound Crystallography Chalcogen Monomer chemistry Density functional theory Physical and Theoretical Chemistry Lone pair
Zdroj:	Inorganic Chemistry. 37:354-359
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic970680f
Popis:	Density functional theory (DFT) calculations have been used to investigate the process of dimerization for the three chalcogen diimides MeNENMe (E = S, Se, Te). DFT calculations for these monomers reveal that the energies of the syn,syn and syn, anti isomers differ by
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6facf670787618632bd0f337ad792752 https://doi.org/10.1021/ic970680f Zobrazit plný text záznamu