Influence of Coulomb effects on the resolving power of multireflection mass-spectrometer systems

Autor: Alexander Makarov, D E Greenfield, I. A. Kopaev, S. S. Alimpiev, M. G. Skoblin, Mikhail A. Monastyrskiy
Rok vydání: 2015
Předmět:
Zdroj: Quantum Electronics. 45:1171-1178
ISSN: 1468-4799
1063-7818
Popis: General theoretical approaches to the modelling of Coulomb effects in short ion bunches, developed previously by the authors, are applied in this paper to the calculation of multireflection mass-spectrometer systems. A separate module of the MASIM 3D applied software package is designed. An adaptive computational procedure for calculating the 'mirror potential' induced by an ion bunch on the surface of field-forming electrodes is proposed. The dynamics of ion bunches in a time-of-flight reflectron-type mass analyser is calculated and the limitations on the resolving power, caused by resonant Coulomb effects of self-bunching and coalescence in the groups of particles with close masses, are revealed on the basis of numerical experiments.
Databáze: OpenAIRE