A new 3d-4f heterometallic selenite chloride with a distorted Shastry-Sutherland lattice
| Autor: | Zhiying Zhao, Yaxin Xie, Zhangzhen He, Mengsi Zhang, Wanwan Zhang, Xing Huang |
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| Rok vydání: | 2020 |
| Předmět: |
Materials science
02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Chloride Magnetic susceptibility Heat capacity Hydrothermal circulation 0104 chemical sciences Electronic Optical and Magnetic Materials Inorganic Chemistry Crystallography Lattice (order) Materials Chemistry Ceramics and Composites medicine Antiferromagnetism Condensed Matter::Strongly Correlated Electrons Physical and Theoretical Chemistry 0210 nano-technology medicine.drug Monoclinic crystal system |
| Zdroj: | Journal of Solid State Chemistry. 286:121315 |
| ISSN: | 0022-4596 |
| Popis: | A new 3d-4f heterometallic selenite chloride FeNd2(SeO3)4Cl has been successfully synthesized by a conventional hydrothermal method. The compound crystallizes in the monoclinic space group C2/C, in which the Fe-layers show an irregular triangle motif and the Nd-layers feature a distorted Shastry-Sutherland lattice. Magnetic measurements show that the compound does not show any peaks of magnetic susceptibility but shows a sharp peak in the heat capacity data under different fields, indicating a possible “hidden antiferromagnetic ordering behavior” in the system. Also, a field-induced magnetic transition is obtained in the magnetization curve. |
| Databáze: | OpenAIRE |
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