Conformationally dependent heavy atom effect of chlorine on alkene triplet lifetimes. Experimental and ab initio calculations

Autor:	T. R. Furlani, E. Ann Nalley, J. Laboy, Lance D. Jacobs, Richard A. Caldwell
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Chemistry Alkene chemistry.chemical_element General Chemistry Biochemistry Catalysis Propene chemistry.chemical_compound Colloid and Surface Chemistry Hydrocarbon Ab initio quantum chemistry methods Computational chemistry Atom Chlorine Molecule Triplet state
Zdroj:	Journal of the American Chemical Society. 114:1623-1625
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00031a013
Popis:	The heavy atom effect of vinyl Cl in enhancing ISC rates of arylalkene triplets is shown to be much greater for substrates which can access nonplanar conformations. The experimental results are consistent with ab initio calculations of spin-orbit coupling
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6f8d86adc8065f42ce92c2df9468d086 https://doi.org/10.1021/ja00031a013 Zobrazit plný text záznamu