Synthesis and reactions of 1-R-3-benzoyl-5-ethoxycarbonyl-6-oxo-1,2,3,6-tetrahydropyridine-2-thiones

Autor: Eduard B. Rusanov, A. N. Esipenko, M. O. Lozinskii, Alexander N. Chernega, V. N. Britsun
Rok vydání: 2007
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 43:1411-1419
ISSN: 1573-8353
0009-3122
DOI: 10.1007/s10593-007-0218-3
Popis: Cycloacylation of N-R-3-oxo-3-phenylpropanethioamides by diethyl ethoxymethylenemalonate occurs selectively to form 1-R-3-benzoyl-5-ethoxycarbonyl-6-oxo-1,2,3,6-tetrahydropyridine-2-thiones which are convenient starting materials for the synthesis of bi-and tricyclic hetero systems including the previously unknown 9-R-7-ethoxycarbonyl-5-phenyl-8,9-dihydropyrido[2,3-d][1,2,4]triazolo[1,5-a]-pyrimidin-8-ones.
Databáze: OpenAIRE