Dispersion and rheological studies of Y-PSZ tape casting slurry

Autor: Raghu Natarajan, K. Sasidharan, K. G. Vasantha Kumari, M. Sapna
Rok vydání: 2005
Předmět:
Zdroj: Bulletin of Materials Science. 28:103-108
ISSN: 0973-7669
0250-4707
DOI: 10.1007/bf02704227
Popis: Different solvent systems in combination with three different dispersants were tried to find out the suitable solvent-dispersant combination, which give optimum dispersion of PSZ. Based on sedimentation, viscosity and rheology characteristics, zeotropic ethanol : xylene with a ratio of 50 : 50 along with 0.5 wt% phosphate ester was found to be the best solvent and dispersant combination. Optimized tape casting slurry was prepared using PEG 600 and BBP as plasticizers and PVB as the binder. Cyclohexanone was used as the homogenizer. The optimized slurry composition with 58% solid loading exhibited shear-thinning pseudoplastic rheological behaviour. Y-PSZ tapes of ∼ 50 Μm thickness free from visible defects were cast with a green tape density of 55%.
Databáze: OpenAIRE