Preparation of single-handed helical phenolic resin nanofibers using a supramolecular templating method

Autor:	Hao Chen, Yi Li, Yong-Min Guo, Li-Qing Ma, Baozong Li
Rok vydání:	2014
Předmět:	inorganic chemicals Circular dichroism Materials science Transmission electron microscopy Scanning electron microscope Nanofiber Amphiphile Polymer chemistry technology industry and agriculture Supramolecular chemistry General Chemistry Diffuse reflection Chirality (chemistry)
Zdroj:	Chinese Chemical Letters. 25:1363-1366
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2014.05.035
Popis:	Single-handed helical phenolic resin nanofibers were synthesized through a supramolecular templating approach using the supramolecular self-assemblies of a pair of chiral low-molecular-weight amphiphiles as the templates and 2,4-dihydroxybenzoic acid and formaldehyde as the precursors. The phenolic resin nanofibers were characterized using field-emission scanning electron microscopy, transmission electron microscopy and diffused reflection circular dichroism. The results indicated that the chirality of the supramolecular self-assemblies was successfully transferred to the phenolic resin nanofibers. The left- and right-handed helical phenolic resin nanofibers exhibited opposite optical activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6f6a58c0550e0d29b062dc8b40efbb0b https://doi.org/10.1016/j.cclet.2014.05.035 Zobrazit plný text záznamu Full Text from ScienceDirect