Reaction of perfluoro-2-azapropene with trialkyl phosphites
Autor: | N. A. Til'kunova, E. G. Bykhovskaya, I. L. Knunyants, A. F. Gontar |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2212-2214 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00923663 |
Popis: | 1. Perfluoro-2-azapropene is more electrophilic than perfluoroisobutylene, which is the most electrophilic of the nonfunctional fluoroolefins. 2. The reaction of perfluoro-2-azapropene with trialkyl phosphites gave trialkoxyperfluoroazapropenylfluorophosphoranes, which are stable intermediate products of the Arbuzov reaction. 3. The trialkoxyperfluoroazapropenylfluorophosphoranes when heated decompose, to the alkyl fluoride, dialkyl fluorophosphate, and trifluoromethylisonitrile. |
Databáze: | OpenAIRE |
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