Reaction of perfluoro-2-azapropene with trialkyl phosphites

Autor: N. A. Til'kunova, E. G. Bykhovskaya, I. L. Knunyants, A. F. Gontar
Rok vydání: 1977
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2212-2214
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00923663
Popis: 1. Perfluoro-2-azapropene is more electrophilic than perfluoroisobutylene, which is the most electrophilic of the nonfunctional fluoroolefins. 2. The reaction of perfluoro-2-azapropene with trialkyl phosphites gave trialkoxyperfluoroazapropenylfluorophosphoranes, which are stable intermediate products of the Arbuzov reaction. 3. The trialkoxyperfluoroazapropenylfluorophosphoranes when heated decompose, to the alkyl fluoride, dialkyl fluorophosphate, and trifluoromethylisonitrile.
Databáze: OpenAIRE