Synthesis, structural and optical characterization of APbX3 (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials
| Autor: | Alessandro Mancini, Angelo Sironi, Massimo Boiocchi, Giuseppe Amoroso, Lorenzo Malavasi, Giorgio Guizzetti, Chiara Milanese, Paolo Quadrelli, Maddalena Patrini |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
Scattering 02 engineering and technology Crystal structure Photoelectric effect 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Electronic Optical and Magnetic Materials Ion Characterization (materials science) Inorganic Chemistry Absorption edge X-ray crystallography Materials Chemistry Ceramics and Composites Physical chemistry Physical and Theoretical Chemistry Absorption (chemistry) 0210 nano-technology |
| Zdroj: | Journal of Solid State Chemistry. 240:55-60 |
| ISSN: | 0022-4596 |
| Popis: | In this paper we report the synthesis, the crystal structure and the optical response of APbX3 (A=MA, DMA, and TMA; X=I, Br) hybrid organic-inorganic materials including some new phases. We observe that as the cation group increases in size, the optical absorption edge shifts to higher energies with energy steps which are systematic and independent on the anion. A linear correlation between the optical bad gap and the tolerance factor has been shown for the series of samples investigated. |
| Databáze: | OpenAIRE |
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