Electrophilic aromatic chlorine cation (Cl+) addition and CO.bul.+ substitution in the gas phase

Autor:	Marcos N. Eberlin, R. Graham Cooks, Brian J. Shay, Tapio Kotiaho
Rok vydání:	1993
Předmět:	Chemical ionization Inorganic chemistry General Chemistry Electrophilic aromatic substitution Anisole Biochemistry Catalysis Nitrobenzene chemistry.chemical_compound Colloid and Surface Chemistry Aniline chemistry Chlorobenzene Reagent Electron ionization
Zdroj:	Journal of the American Chemical Society. 115:1004-1014
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00056a027
Popis:	Chlorine cation addition to benzene, aniline, anisole, styrene, chlorobenzene, and nitrobenzene was studied using NH 3 Cl + , ClC≡O + , protonated CH 3 Cl, and Cl + as reagent ions. The reactions of protonated monochloramine were followed using a direct insertion membrane probe for sample introduction and a pentaquadrupole mass spectrometer for product characterization. The other reagent ions ClC≡O + , Cl + , and protonated CH 3 Cl were generated by electron ionization of acetyl chloride and carbon tetrachloride and by methane chemical ionization of CH 3 Cl, respectively
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6f2e2df004ee5ffae5809208074a4b7b https://doi.org/10.1021/ja00056a027 Zobrazit plný text záznamu