Graphene oxide nanosheets-catalyzed synthesis of novel benzylbarbiturocoumarin derivatives under green conditions
| Autor: | Bahador Karami, Khalil Eskandari |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Green chemistry
Barbituric acid 010405 organic chemistry Graphene Aryl Oxide General Chemistry Bond formation 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis law.invention chemistry.chemical_compound chemistry law 4-Hydroxycoumarin Organic chemistry |
| Zdroj: | Monatshefte für Chemie - Chemical Monthly. 147:2119-2126 |
| ISSN: | 1434-4475 0026-9247 |
| DOI: | 10.1007/s00706-016-1724-8 |
| Popis: | An efficient tricomponent reaction between barbituric acid (or N,N-dimethylbarbituric acid), 4-hydroxycoumarin, and a wide range of aryl aldehydes to obtain novel benzylbarbiturocoumarins is described. Starting materials were successfully condensed via three C–C bond formation by graphene oxide nanosheets as an efficient, metal-free, environmentally safe, and recyclable nanocatalyst to obtain target products. The target products were obtained with high selectivities and yields (80–88 %) in H2O/EtOH (1:1) in the presence of graphene oxide nanosheets (0.005 g) at 80 °C. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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