Kinetics and thermodynamics of the electroreduction of buckminsterfullerene in benzonitrile

Autor:	Marcin Opallo, Milan Fedurco, W. Ronald Fawcett, Joong W. Lee
Rok vydání:	1993
Předmět:	Reaction mechanism Fullerene Kinetics Thermodynamics General Chemistry Electrolyte Electrochemistry Biochemistry Catalysis chemistry.chemical_compound Benzonitrile Colloid and Surface Chemistry Buckminsterfullerene Reaction rate constant chemistry Physical chemistry
Zdroj:	Journal of the American Chemical Society. 115:196-200
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00054a027
Popis:	The kinetics and thermodynamics C 60 the reduction of buckminsterfullerene (C 60 ) have been studied in benzonitrile solutions containing tetraalkylammonium salts as electrolytes. On the basis of the observed shifts in half-wave potential with electrolyte concentration, it is shown that the resulting anions from the first and second reduction steps, namely C 60 - and C 60 2- are associated with two or more tetraalkylammonium cations
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6ef9a80f7ed009ef167f2616dcc7f118 https://doi.org/10.1021/ja00054a027 Zobrazit plný text záznamu