A Method for Microscale Combustion of Near Stoichiometric Energy Dense Liquid Fuel Mixtures

Autor: W R Allmon, C.M. Waits, E D Tolmachoff
Rok vydání: 2013
Předmět:
Zdroj: Journal of Physics: Conference Series. 476:012074
ISSN: 1742-6596
1742-6588
DOI: 10.1088/1742-6596/476/1/012074
Popis: This paper reports on the potential of a heterogeneous/homogeneous (HH) reactor for use as a fuel-flexible heat source, meeting the needs of the next generation of high temperature thermal-to-electric (TEC) portable power converters. In this class of reactor, low activation energy catalytic reactions provide a means to stabilize high activation energy homogeneous reactions. Diffusion limited surface reactions play a critical role in HH reactor operation. Surface conversion must be sufficiently fast to generate the high temperatures (~1000 K) necessary to initiate gas phase reactions. Therefore, fuel diffusivity and the reactor dimension are important parameters in governing HH reactor operation. We examine the performance of an HH reactor fuelled by propane and n-dodecane, representing two extremes of liquid hydrocarbon diffusivity, as a function of confining reactor dimension. Unburned fuel/air mixtures are close to stoichiometric, which is an important factor in minimizing the amount of excess air and, therefore, balance of plant energy costs. At moderate levels of confinement, the reactor is capable producing high, uniform temperatures for both fuels.
Databáze: OpenAIRE