Popis: |
In the late 1990s, large amounts of low permeability resource plays in the south of Songliao basin have been discovered and made a great contribution to regional development, so far most of them need to be made efforts to improve recovery factors by tertiary method, CO2 flooding has an effective way for this kind of reservoir. CO2 injection pilot was implemented in 2008, it provided invaluable information for extensive areas to make gas injection and production scheme including produced gas recycling. Most low permeability reservoirs in Song Liao basin have no nature flow, the economic productivity could not be obtained except fracturing. Therefore, it leads to CO2 breakthrough early and produced gas profile variation greatly during the CO2-EOR process. CO2 is from the deeper natural gas field with CO2 concentration over 20%, after separation, the CO2 purity reaches 99% for injection. So how to treat the EOR produced gas is an environmental and economic issue to achieve zero emissions for the whole operations. According to the actual field test data, the vast majority of composition of produced gas are lighter hydrocarbon and CO2. This paper will analyze the composition of gas samples from Jilin oil field, understanding the components of the output gas variation with time. The phase behavior and mass transfer will be characterized by the minimum miscibility pressure (MMP) test and core flood experiment, and the quantitative description method will be obtained through the relationship between the individual component or segment components and sweep efficiency. Consideration the effect of CO2 impurities on MMP and displacement efficiency, the critical value of CO2 concentration of produced gas is 85%~95%, according to this study, all the produced gas can be reinjection without separation, the value for field application is approximately 90%. That means it would require mixing with pure CO2 for reinjection when CO2 concentration of produced gas is below 90%, otherwise, it could re-inject to oil field directly. All these results have been applied to achieve reasonable CO2 recycle. |