| Popis: |
The synthesis of a photosubstrate (42) suitable for the production of a Dewar furan (46) containing a four-carbon bridge at the 1,4-position is described. The route to this product illustrates an example of transfer technology in synthesis, by using the oxanorbornadiene (29). Other active species such as Dewar benzene (32) and Dewar o-xylylene (50) play key roles as intermediates. Diels-Alder cycloadditions are also central to the overall strategy, and some observations are made regarding the facial specificities operating, especially in regard to Dewar o-xylylene (50) and its dimerization. Attempts to isolate the photoproducts, presumably involving the Dewar furan (46) as intermediate, were unsuccessful. |
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