Structural Stability of (Ba,Sr)RuO 3 Electrodes on Hydrogen Annealing and Effect of interfacial Layers in (Ba,Sr)TiO 3 Thin Films

Autor: Sang-Shik Park, Soon-Gil Yoon, Eun-Suck Choi
Rok vydání: 2002
Předmět:
Zdroj: Integrated Ferroelectrics. 47:31-40
ISSN: 1607-8489
1058-4587
DOI: 10.1080/713718271
Popis: (Ba,Sr)RuO 3 (BSR) electrodes were deposited on n-type Si (100) substrates by liquid-delivery metalorganic chemical vapor deposition (LDMOCVD) and their stability in a hydrogen ambient was investigated. BSR films showed the structural and morphological stability when annealed in hydrogen forming gas (4 % H 2 +96% balance N 2 ) temperatures of up to 500 ¯ . The abrupt increase of resistivity with increasing hydrogen annealing temperature can be attributed to oxygen loss in BSR films without phase change and was completely recovered by annealing at 700 ¯ in an O 2 ambient. The dielectric constant of the Pt/BSR/BST/Pt structures increased with increasing BSR interfacial layers. The dielectric constant of a BSR/BST/Pt capacitor with a 35 nm thick BST without top Pt electrode showed about 425.
Databáze: OpenAIRE