Living Free Radical Polymerizations Mediated by the Reversible Combination of Transient Propagating and Persistent Nitroxide Radicals. The Role of Hydroxylamine and Alkene Formation
| Autor: | Marc Souaille, Hanns Fischer |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
Nitroxide mediated radical polymerization Polymers and Plastics Alkene Radical Organic Chemistry Radical polymerization Side reaction Nitroxyl Photochemistry Inorganic Chemistry chemistry.chemical_compound Hydroxylamine chemistry Materials Chemistry Radical disproportionation |
| Zdroj: | Macromolecules. 34:2830-2838 |
| ISSN: | 1520-5835 0024-9297 |
| DOI: | 10.1021/ma001886u |
| Popis: | A kinetic analysis of living polymerizations controlled by persistent nitroxide radicals is extended to cover the formation of hydroxylamines and alkene macromonomers. This reaction can occur by ra... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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