On the complete analysis of continuous wave transient ESR spectra

Autor:	M. T. Yeung, K. A. Mclauchlan
Rok vydání:	1996
Předmět:	Esr spectra Hyperfine coupling Nuclear magnetic resonance Chemistry Biophysics Continuous wave Physical and Theoretical Chemistry Atomic physics Condensed Matter Physics Polarization (waves) Molecular Biology Microwave Spectral line
Zdroj:	Molecular Physics. 89:1423-1443
ISSN:	1362-3028 0026-8976
DOI:	10.1080/002689796173273
Popis:	It is demonstrated that accurate values of the parameters, such as relaxation times, which determine the appearance of transient ESR spectra and, to some extent their time-dependence, can be obtained from analysis of the oscillation patterns observed at high microwave field strengths. A new methodology is introduced for this, which also allows more accurate determination of hyperfine coupling constants. This opens the route to precise simulation of polarized spectra and to the identification of the radical pairs from which the polarization results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6e52de38f6aa36219c9d0ecc0335378a https://doi.org/10.1080/002689796173273 Zobrazit plný text záznamu