A magnetic metal/polymer nanocomposite material based on poly(diphenylamine) and Fe3O4 nanoparticles

Autor:	S. Zh. Ozkan, Petr A. Chernavskii, Mikhail N. Efimov, Ella L. Dzidziguri, Galina N. Bondarenko, G. P. Karpacheva
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Nanocomposite Polymer nanocomposite Diphenylamine General Chemistry Polymer Metal chemistry.chemical_compound chemistry Chemical engineering visual_art visual_art.visual_art_medium Organic chemistry Thermal stability Powder diffraction Superparamagnetism
Zdroj:	Russian Chemical Bulletin. 64:196-201
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-015-0842-5
Popis:	It was discovered that IR heating of poly(diphenylamine) in the presence of FeCl3•6H2O in an inert atmosphere at 300–700 °C produces a metal polymer nanocomposite with Fe3O4 nanoparticles dispersed in polymer matrix. This is achieved by condensation of crystalline diphenylamine oligomers with evolution of hydrogen that promotes iron reduction. The formation of Fe3O4 nanoparticles was confirmed by X-ray powder diffraction. The magnetic and thermal properties of the Fe3O4—poly(diphenylamine) nanocomposite were examined. This nanocomposite material shows superparamagnetism and thermal stability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6e3c132dfab80e4fd8b29807eb3dba78 https://doi.org/10.1007/s11172-015-0842-5 Zobrazit plný text záznamu Full text from SpringerLink