Synthesis of l-idofuranurono-6,3-lactone and its derivatives via hexodialdodifuranoses

Autor:	Karl Dax, Hans Weidmann, Ingolf Macher, Erich Wanek
Rok vydání:	1980
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Lactol Stereochemistry Hydrogenolysis Organic Chemistry Glycoside General Medicine Biochemistry Lactone Analytical Chemistry
Zdroj:	Carbohydrate Research. 80:45-51
ISSN:	0008-6215
Popis:	1,2- O -Alkylidene-β- l -idofuranurono-6,3-lactones were obtained from the corresponding 5- O -toluene- p -sulphonyl-α- d -glucofuranurono-6,3-lac tones by a sequence involving lactone reduction, benzoylation of HO-6, inversion of configuration at C-5, deacylation, and lactol oxidation. Hydrogenolysis or methanolysis of 1,2- O - benzylidene-β- l -idofuranurono-6,3-lactone gave l -idofuranurono-6,3-lactone and a mixture of its methyl glycosides, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6e1a600bdfe52733b12222d7b8b1eb63 https://doi.org/10.1016/s0008-6215(00)85313-6 Zobrazit plný text záznamu