Cooperative influence of H2 and C2H4 molecules on theb-a anda-X transitions in the O2 molecule in a ternary complex

Autor:	N. M. Ivanova, I. V. Fedulova, B. F. Minaev, Z. M. Muldakhmetov, G. I. Kobzev
Rok vydání:	2000
Předmět:	Chemical physics Chemistry Transition dipole moment Molecule chemistry.chemical_element Atomic physics Condensed Matter Physics MINDO Ternary complex Oxygen Spectroscopy
Zdroj:	Journal of Applied Spectroscopy. 67:617-622
ISSN:	1573-8647 0021-9037
DOI:	10.1007/bf02681294
Popis:	Moments of the b-a and a-X transitions induced in an oxygen molecule by collision in the O2 + C2H4 + H2 complex are calculated by the semiempirical MINDO/3 method with allowance for the spin-orbital interaction. On the basis of two collisional models it is shown that the cooperative influence of C2H4 and H2 molecules can be both enhancing and weakening as compared with their individual influence. Here, the relative location of the oxygen molecule and its surroundings plays an important role.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6e0367651b7dcd4c9f06558dd564569f https://doi.org/10.1007/bf02681294 Zobrazit plný text záznamu Full text from SpringerLink