Synthesis and structure of 2D- and 3D- inorganic-organic coordination polymers: based on Ag-hmt subunit

Autor:	Yanxiong Ke, Sheming Lu, Wenxin Du, Xintao Wu, Shoubo Qin, Hongxia Pei, Shuxi Zhou, Jianmin Li
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Coordination polymer Tar General Chemistry Polymer Crystal structure Condensed Matter Physics Solvent chemistry.chemical_compound Crystallography chemistry X-ray crystallography Molecule General Materials Science Hexamethylenetetramine
Zdroj:	Crystal Research and Technology. 39:89-93
ISSN:	1521-4079 0232-1300
DOI:	10.1002/crat.200310154
Popis:	Two new inorganic-organic complexes, namely, [Ag2(hmt)2]Cr2O7·H2O (1) and [Ag(hmt)(tar)0.5]·H2O (2), (hmt = hexamethylenetetramine, Tar = tartarate,), have been synthesized in H2O/CH3CN solvent at room temperature. Both molecules have the common [Ag3hmt3]3+ layers. Compound 1 is a two-dimensional structure, and Complex 2 shows three-dimensional topology. In complex 2, the tartarate molecules are connected with adjacent layers to form parallelogram pores of 18.55×7.44 A, which are occupied by two water molecules. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
Databáze:	OpenAIRE
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