Selective catalytic reduction of NO with methane over indium supported on tungstated zirconia

Autor:	Dong Yang, Chongli Song, Mingfen Wen, Junhua Li
Rok vydání:	2007
Předmět:	Process Chemistry and Technology Inorganic chemistry chemistry.chemical_element Selective catalytic reduction General Chemistry Manganese Catalysis Metal Nickel chemistry visual_art visual_art.visual_art_medium Cobalt NOx Indium
Zdroj:	Catalysis Communications. 8:2243-2247
ISSN:	1566-7367
DOI:	10.1016/j.catcom.2007.04.035
Popis:	Selective catalytic reduction (SCR) of NOx with methane was investigated over a series of non-noble metal (cobalt, manganese, nickel, tin, silver, indium) catalysts supported on tungstated zirconia (WZr). A great improvement of catalytic activity was found over the indium-loaded WZr catalysts upon the other WZr. The highest NOx conversion of 70% was achieved over an 1%In/WZr catalyst at 450 °C and 12,000 h−1. InO+ was proposed to be the active site in NO reduction. H2O and SO2 significantly inhibited NO reduction by competing with reactants to adsorb on InO+ site and forming inactive In ( OH ) 2 + and In(SO3)+ species.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6df8af24e944143fb741cc7afd9d33b5 https://doi.org/10.1016/j.catcom.2007.04.035 Zobrazit plný text záznamu Full Text from ScienceDirect