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The results of theoretical, experimental investigations on activation of small molecules on their coordination to cluster complexes of heavy transition metals with weak- and strong-field ligands are presented. Homogeneous catalytic redox reactions of the CO, N2, H2O molecules and the N3- molecular anion in the presence of cluster complexes of low-valent molybdenum and rhenium are studies. The reaction mechanism is established. Three modifications of the homogeneous cluster catalysis of redox reactions of small molecules are described. |
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