Autor:	V. L. Lobachev, Yu. V. Geletii, E. S. Rudakov, G. P. Zimtseva, S. L. Kluger
Rok vydání:	2003
Předmět:	Peroxynitrous acid chemistry.chemical_compound Reaction mechanism Chemistry Radical Inorganic chemistry Kinetics Substrate (chemistry) General Chemistry Selectivity Photochemistry
Zdroj:	Theoretical and Experimental Chemistry. 39:41-47
ISSN:	0040-5760
DOI:	10.1023/a:1022950227702
Popis:	The kinetic features of the oxidation of alkenes by peroxynitrous acid (HOONO) generated in the H2O2–HNO2/acetate buffer (pH 4.27) system, are quantitatively explained assuming simultaneous reactions in the gas and liquid phases. A remarkable similarity is found for the substrate selectivities of the gas-phase reactions of alkenes as well as of alkanes and arenes with HOONO and with ·OH radicals. The reaction mechanism is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6dda98566e341c6fcac80d2d3148efd1 https://doi.org/10.1023/a:1022950227702 Zobrazit plný text záznamu Full text from SpringerLink