ChemInform Abstract: Diastereoselective Homogeneous Hydrogenations Without Direction by Substituents

Autor: Edward J. Farrington, John M. Brown, Mauro Comes Franchini
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 29
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.199819055
Popis: The Rh complex catalysed hydrogenation of an α-(hydroxyalkyl)- N-methoxyacrylamide and the Ru complex catalysed hydrogenation of an α-(fluoroalkyl)acrylate both proceed with ≥90% selectivity to give the syn-isomer.
Databáze: OpenAIRE