Alkylation of (As, Sb, Bi)Cl3: formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CHC)(SiMe3)(C5H4N-2)] and 2-CH(SiMe3)2C5H4N-5-R [R = C(SiMe3)2C5H4N-2]
Autor: | Allan H. White, W.C. Patalinghug, Peter C. Junk, Colin L. Raston, Cameron Jones, Lutz M. Engelhardt, David S. Hutchings |
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Rok vydání: | 1991 |
Předmět: | |
Zdroj: | J. Chem. Soc., Chem. Commun.. :1560-1562 |
ISSN: | 0022-4936 |
Popis: | Monomeric alkyldichloro-antimony(III) and –bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H4N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CHC)(SiMe3)(C5H4N-2)] where the C2 insertion–SiMe3 elimination fragment originates from THF, and the ‘head-to-tail’ alkyl coupled species, 2-CH(SiMe3)2C5H4N-5-R. |
Databáze: | OpenAIRE |
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