Alkene aziridination and epoxidation catalyzed by chiral metal salen complexes

Autor:	Kenneth J. O'Connor, Cynthia J. Burrows, S.‐J. Wey
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Silylation Metal salen complexes Chemistry Alkene Organic Chemistry Drug Discovery Polymer chemistry Organic chemistry Chirality (chemistry) Biochemistry Asymmetric induction Catalysis
Zdroj:	Tetrahedron Letters. 33:1001-1004
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)91844-6
Popis:	New chiral metal salen complexes substituted in the 3 position with bulky silyl groups (TMS, TBDMS) have been synthesized. Although some of these complexes catalyzed the epoxidation of unfunctionalized olefins in moderate to high ee's, they catalyzed the aziridination of cis-β-methylstyrene without any asymmetric induction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6d501d9487aa1671605b0e1f98c97c62 https://doi.org/10.1016/s0040-4039(00)91844-6 Zobrazit plný text záznamu