Reactions of acetylenes with noble-metal carbonyl halides. 12. Synthesis, reactivity, and solution structures by multinuclear NMR studies of .sigma.-alkenylplatinum(II) complexes. X-ray structure analysis of [cyclic][Pt{C(C6H5):C(H)C(:O)Me}(CO)Cl] and [Pt{C(C6H5):C(H)C(:NC6H5)Me}(PPh3)2Cl]

Autor:	Claudio Allevi, Fabio Ganazzoli, Luigi Garlaschelli, Maria Carlotta Malatesta
Rok vydání:	1990
Předmět:	Chemistry Stereochemistry Organic Chemistry Nuclear magnetic resonance spectroscopy Crystal structure Metallacycle Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Aniline X-ray crystallography Molecule Reactivity (chemistry) Physical and Theoretical Chemistry Triphenylphosphine
Zdroj:	Organometallics. 9:1383-1391
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om00119a005
Popis:	La reaction de [Pt(CO) 2 ] 3n 2− avec H [Pt(CO)Cl 3 ] et C 6 H 5 C≡CC(O)Me donne un complexe oxo-3 phenyl-1 butene-1 yl du platine qui reagit avec PPh 3 pour conduire au complexe [Pt{C(C 6 H 5 )=C(H)C(=O)Me}(PPh 3 )Cl]. Sa reaction avec des amines aromatiques puis avec PPh 3 donne les complexes [Pt{C(C 6 H 5 )=C(H)C(=NC 6 H 5 )Me}(PPh 3 )Cl] et [Pt{C(C 6 H 5 )=C(H)C(=NC 6 H 5 )Me}(PPh 3 )Cl]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6d4f84e75e8e57a445356d98f733d1a3 https://doi.org/10.1021/om00119a005 Zobrazit plný text záznamu