Czochralskiite, Na4Ca3Mg(PO4)4, a second new mineral from the Morasko IAB-MG iron meteorite (Poland)
| Autor: | Łukasz Karwowski, Katarzyna Helios, Ryszard Kryza, Piotr Drożdżewski, Evgeny V. Galuskin, Joachim Kusz, Andrzej Muszyński |
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| Rok vydání: | 2016 |
| Předmět: |
Mineralogy
engineering.material 010502 geochemistry & geophysics 01 natural sciences Iron meteorite Troilite Cohenite chemistry.chemical_compound Crystallography Kosmochlor Daubréelite Schreibersite Sphalerite chemistry Geochemistry and Petrology 0103 physical sciences engineering Whitlockite 010303 astronomy & astrophysics Geology 0105 earth and related environmental sciences |
| Zdroj: | European Journal of Mineralogy. 28:969-977 |
| ISSN: | 0935-1221 |
| DOI: | 10.1127/ejm/2016/0028-2557 |
| Popis: | Czochralskiite, Na 4 Ca 3 Mg(PO 4 ) 4 , is the second new phosphate mineral found in the Morasko IAB-MG iron meteorite. This very rare mineral occurs in phosphate inclusions (nodules) with graphite rims enclosed in the kamacite–taenite matrix of the meteorite. Almost thirty mineral species have been reported from this meteorite (most from various inclusions), including six, possibly eight phosphates (fluorapatite, buchwaldite, brianite, merrillite, moraskoite Na 2 Mg(PO 4 )F, chlorapatite? and whitlockite?), and schreibersite, chromite, enstatite (‘bronzite’), kosmochlor, kosmochlor–augite, olivine, albite, orthoclase, quartz, cohenite, nickelphosphide, altaite, troilite, pyrrhotite, sphalerite, daubreelite, djerfisherite, and native Cu. Czochralskiite forms xenomorphic, usually oval grains and amoeboid aggregates, between 0.1 and 0.5 mm in size. It is colourless and transparent, with white streak and vitreous lustre; it shows no fluorescence, it is biaxial (+): α = 1.608(2), β = 1.611(2), γ = 1.616(2); α = a , β = b , γ = c ; 2 V (meas.) = 70° (10), 2 V (calc.) = 76°; the dispersion is very weak; Mohs’ hardness is 4–5; the fracture is irregular, conchoidal, and no cleavage was observed. The mean of twelve electron-microprobe analyses is (wt%): P 2 O 5 46.28, CaO 27.59, Na 2 O 20.04, MgO 6.21, FeO 0.32, MnO 0.16, K 2 O 0.09, total 100.69, leading to the empirical formula Na 3.97 Ca 3.02 Mg 0.95 Mn 2+ 0.01 K 0.01 Fe 2+ 0.03 (P 4.00 O 16 ). The calculated density based on the empirical formula and the single-crystal structural data is 3.148 g · cm −3 . The structure of czochralskiite [ Pnma, a = 17.9230(2), b = 10.7280(2), c = 6.7794(1) A, V = 1303.53(3)A 3 , Z = 4] is of the glaserite-type and related to that of buchwaldite and brianite. The strongest diffraction lines of the calculated czochralskiite powder diffraction pattern are [ d hkl (I )]: 3.802(48), 3.728(31), 2.726(100), 2.679(63), 2.602(83), 1.901 (44). The Raman spectrum shows the following characteristic bands (cm −1 , strong bands underlined): 1119, 1167, 1053, 1039, 1022, 1011, 986, 974, 966, 606, 585, 578 and 441. The Raman data show the absence of H 2 O and CO 2 . Czochralskiite is interpreted as a primary phosphate, which crystallized together with graphite and other phosphates inside the nodules. The mineral name honours Jan Czochralski (1885–1953), Polish chemist, crystallographer and metallurgist. |
| Databáze: | OpenAIRE |
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