New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes

Autor:	V.A. Vasnev, Boris A. Izmaylov, Galy D. Markova
Rok vydání:	2019
Předmět:	010405 organic chemistry Grignard reaction General Chemistry 010402 general chemistry 01 natural sciences Chloride 0104 chemical sciences chemistry.chemical_compound Transmetalation chemistry Yield (chemistry) medicine Organic chemistry Isomerization medicine.drug
Zdroj:	Mendeleev Communications. 29:194-195
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2019.03.026
Popis:	New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6d0db28ff2339303a9df19aeef26c723 https://doi.org/10.1016/j.mencom.2019.03.026 Zobrazit plný text záznamu Full Text from ScienceDirect