Electrochemical studies of Schiff base compounds derived from antipyrine nucleus in ethanolic buffer solutions

Autor: Y. I. Moharram, Ibrahim S. El-Hallag, G. B. El-Hefnawy, Enass M. Ghoneim
Rok vydání: 2000
Předmět:
Zdroj: Canadian Journal of Chemistry. 78:1170-1177
ISSN: 1480-3291
0008-4042
DOI: 10.1139/v00-108
Popis: The electrochemical behaviour of Schiff base compounds derived from an antipyrine nucleus was investigated in 30% (v/v) ethanolic buffer solutions (pH 3-11) using various electrochemical techniques at mercury electrode. The results showed that, the total limiting current of each of the studied compounds corresponds to 2-electron transfer process. The mechanistic pathway of the electrode reaction of the investigated compounds at mercury electrode, the effect of the medium, and the evaluation of the electrode reaction parameters were illustrated and discussed.Key words: Schiff base, antipyrine nucleus, electrode reaction, electrochemical parameters, cyclic voltammetry.
Databáze: OpenAIRE