Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel–Crafts acylations

Autor: Jean Roger Desmurs, Alain Dormond, Fanny Duris, Jean Marie Bernard, Denise Barbier-Baudry
Rok vydání: 2002
Předmět:
Zdroj: Journal of Molecular Catalysis A: Chemical. 188:97-104
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(02)00341-2
Popis: The use of catalytic amounts: 1 mol% or less of perfluoroalkyl lanthanide salts as homogeneous catalysts for Friedel–Crafts acylations in non-hazardous solvents is thereafter investigated. Lanthanide bis(trifluoromethylsulfonyl)amides are better catalysts than the triflate analogues towards the acetylation of activated aromatic rings.
Databáze: OpenAIRE