Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel–Crafts acylations
Autor: | Jean Roger Desmurs, Alain Dormond, Fanny Duris, Jean Marie Bernard, Denise Barbier-Baudry |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Journal of Molecular Catalysis A: Chemical. 188:97-104 |
ISSN: | 1381-1169 |
DOI: | 10.1016/s1381-1169(02)00341-2 |
Popis: | The use of catalytic amounts: 1 mol% or less of perfluoroalkyl lanthanide salts as homogeneous catalysts for Friedel–Crafts acylations in non-hazardous solvents is thereafter investigated. Lanthanide bis(trifluoromethylsulfonyl)amides are better catalysts than the triflate analogues towards the acetylation of activated aromatic rings. |
Databáze: | OpenAIRE |
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