K-Conservation in the dissociation of singlet ketene

Autor:	C. Bradley Moore, Melonie A. Hall, Elisabeth A. Wade, Axel Mellinger
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Reaction rate constant Chemistry Reaction dynamics General Chemical Engineering Photodissociation Ketene Singlet state Helicity basis Photochemistry Molecular physics Dissociation (chemistry) Excitation
Zdroj:	Berichte der Bunsengesellschaft für physikalische Chemie. 101:465-468
ISSN:	0005-9021
DOI:	10.1002/bbpc.19971010319
Popis:	The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conservation on rate constants is relatively subtle, PHOFEX spectra with state-selected reactant molecules appear to provide a feasible way to experimentally resolve the question of K-conservation.
Databáze:	OpenAIRE
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