Chronopotentiometry of one- and two-ion transport at immiscible liquid interfaces

Autor:	Frederick S. Stover, Owen R. Melroy, Richard P. Buck, Harold C. Hughes
Rok vydání:	1981
Předmět:	Aqueous solution Potential difference Chemistry Real systems Supporting electrolyte Analytical chemistry Thermodynamics Electrolyte Ion transporter
Zdroj:	Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 121:93-114
ISSN:	0022-0728
DOI:	10.1016/s0022-0728(81)80571-2
Popis:	Reversible one-ion and opposite-sign, two-ion univalent transfers from aqueous to organic phases (and the reverse processes) have been analyzed. Solutions of transport and interfacial potential difference equations are given in terms of concentration-distance-time profiles, potential difference vs. time chronopotentiograms and expressions for transition times when they exist. Six cases include supporting electrolyte and non-supporting electrolyte examples. One of these: two-ion, salt transport without supporting electrolyte is the Nernst-Riesenfeld example from which the ideas of electrosorption-desorption arise. Real systems investigated by Gavach and co-workers have received special emphasis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6cdc1b840a1834ad728d7cdf8c1c8ffb https://doi.org/10.1016/s0022-0728(81)80571-2 Zobrazit plný text záznamu