Recovery of flavonoids using novel biodegradable choline amino acids ionic liquids based ATPS
| Autor: | Patricia F. Requejo, Emilia Tojo, Eugénia A. Macedo, Elena Gómez |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Binodal
chemistry.chemical_classification Chromatography Aqueous solution Atmospheric pressure 010405 organic chemistry General Chemical Engineering General Physics and Astronomy 02 engineering and technology 01 natural sciences 0104 chemical sciences Amino acid Partition coefficient Rutin chemistry.chemical_compound 020401 chemical engineering chemistry Ionic liquid 0204 chemical engineering Physical and Theoretical Chemistry Quercetin |
| Zdroj: | Fluid Phase Equilibria. 493:1-9 |
| ISSN: | 0378-3812 |
| DOI: | 10.1016/j.fluid.2019.03.024 |
| Popis: | In this work, different ionic liquids composed by choline as cation and amino acid as anion (CAAILs) have been synthetized and applied to establish aqueous two-phase systems (ATPS) with two phosphate salts. In order to understand the phase formation process of the ATPS, binodal curves, tie-lines and their respective tie-line lengths were determined at T = 298.15 K and atmospheric pressure. Besides, the tie-lines were fitted using Othmer-Tobias and Bancroft equations. Furthermore, with the aim to analyse the application of the studied ATPS in the recovery of flavonoids, partition coefficients of rutin and quercetin were calculated at T = 298.15 K and atmospheric pressure. Finally, the obtained results were compared with those found in literature. |
| Databáze: | OpenAIRE |
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