Multiple redox reactions and electrochromism of bilayer membranes of Prussian blue and Ru(bpy)32+

Autor:	Shousuke Teratani, Masao Kaneko, Kenichi Harashima
Rok vydání:	1992
Předmět:	Prussian blue General Chemical Engineering Bilayer Inorganic chemistry chemistry.chemical_element Photochemistry Electrochemistry Analytical Chemistry Ruthenium chemistry.chemical_compound chemistry Electrochromism Saturated calomel electrode Nafion Cyclic voltammetry
Zdroj:	Journal of Electroanalytical Chemistry. 325:325-332
ISSN:	1572-6657
DOI:	10.1016/0022-0728(92)80122-k
Popis:	Redox reactions and electrochromism of bilayer membranes of Prussian blue (PB) and Nafion containing Ru(bpy)32+ coated on ITO electrodes were s scanning from −0.5 V to 1.5 V (saturated calomel electrode). For the ITO/PB/Nafion[Ru(bpy)32+] bilayer system, the cyclic voltammogram as wel (bpy)32+ depending on the applied potentials. However, for the ITO/Nafion[Ru(bpy)32+]/PB bilayer system, PB was not reduced on scanning oxidation of the ruthenium complex. Both the systems exhibited multielectrochromism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6cd7f4ca4160623014101cba9910c723 https://doi.org/10.1016/0022-0728(92)80122-k Zobrazit plný text záznamu