Synthesis and chiral recognition properties of two novel chiral calix[4]arene tartaric ester derivatives
| Autor: | Ayhan S. Demir, Abdulkadir Sirit, Aysegul Karakucuk, Mustafa Yilmaz, Mustafa Durmaz |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Ester derivatives
Hydrochloride Organic Chemistry Nuclear magnetic resonance spectroscopy Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Tartaric acid Proton NMR Organic chemistry Physical and Theoretical Chemistry Spectroscopy Chiral derivatizing agent Serine methyl ester |
| Zdroj: | Tetrahedron: Asymmetry. 17:1963-1968 |
| ISSN: | 0957-4166 |
| DOI: | 10.1016/j.tetasy.2006.07.011 |
| Popis: | Two new chiral calix[4]arene derivatives containing tartaric acid ester moieties were synthesized. The chiral calix[4]arenes are in a ‘ cone ’ conformation according to NMR spectroscopy. The chiral recognition capabilities of 1 – 4 toward the guests, 1,2-propanediol and serine methyl ester hydrochloride (SerOMe), were investigated ( 1 H NMR spectroscopy). The extraction properties of compounds 1 and 2 toward selected α-amino acid methyl esters were also studied. |
| Databáze: | OpenAIRE |
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