A Rotorlike Supramolecular Assembly, {[K(18-crown-6)]PbI3}∞, with a Reversible Breaking-Symmetry Phase Transition near Room Temperature
| Autor: | Dong-Sheng Shao, Bingwen Hu, Wen-Long Liu, Xiao-Ming Ren, Guo-Jun Yuan |
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| Rok vydání: | 2020 |
| Předmět: |
Phase transition
010405 organic chemistry Chemistry 18-Crown-6 Supramolecular chemistry 010402 general chemistry 01 natural sciences Symmetry (physics) 0104 chemical sciences Supramolecular assembly Inorganic Chemistry Crystal chemistry.chemical_compound Crystallography Chain (algebraic topology) Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 59:980-983 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.9b03517 |
| Popis: | A rotorlike supramolecular crystal, {[K(18-crown-6)]PbI3}∞, is composed of a linear [PbI3]∞ chain acting as a stator and [K(18-crown-6)]+ cations fastened to the [PbI3]∞ chain and K–I bond like rot... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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