Autor:	Peter D. Clark, S. T. E. Mesher, Masood Parvez
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Addition reaction Alkene Cyclohexene General Chemistry Conjugated system Catalysis chemistry.chemical_compound Montmorillonite chemistry Yield (chemistry) Organic chemistry Alkyl
Zdroj:	Catalysis Letters. 47:73-75
ISSN:	1011-372X
DOI:	10.1023/a:1019067929473
Popis:	A mild method for 1,2-addition of alkyl disulfides to alkenes and conjugated polyenes catalysed by MClx-promoted montmorillonite clays is reported. Alkenes undergo 1,2-trans addition affording MClx-complexed derivatives, which are readily converted to alkylthio-derivatives on reaction with EDTA. Conjugated polyenes yield 1,2-trans addition and 1,n-addition products, with 1,2-addition compounds being found at low reaction temperatures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6c8e6f09fd642e23a32cefd07d1162a1 https://doi.org/10.1023/a:1019067929473 Zobrazit plný text záznamu Full text from SpringerLink