Synthesis, сrystal structure and Hirshfeld surface analysis of ciprofloxacinium tetrachlorocadmium dihydrate
| Autor: | Bakhtiyar T. Ibragimov, A. B. Ibragimov, Vahobjon Kh. Sabirov, Aygul Dauletiyarovna Kudiyarova, Jamshid Ashurov |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Salt (chemistry) Protonation General Chemistry Crystal structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Crystal Piperazine chemistry.chemical_compound Crystallography chemistry Tetrachloride Molecule Single crystal |
| Zdroj: | Chemical Data Collections. 31:100633 |
| ISSN: | 2405-8300 |
| DOI: | 10.1016/j.cdc.2020.100633 |
| Popis: | The crystal structure of dihydrate salt between cadmium tetrachloride and ciprofloxacin (L), [CdCl4](HL)2•2H2O (I), L CIP C17H18FN3O3, was determined by the single crystal X-ray diffraction method. The title compound was prepared by mixing of CdCl2 water solution and L•HCl in molar ratio 1:2 and evaporation of mother solution in the room temperature. Crystal structure of I is built from the [CdCl4]2− tetrahedron, two single charged (HL)+ cations and two water molecules. Ciprofloxacin is protonated on the cyclic N(3) atom of the piperazine сycle. The Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H···H (about 35%) and H···O/O···H (around 24%) interactions . |
| Databáze: | OpenAIRE |
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