Intermediate complexes in oxidation reactions catalyzed by Rh(I) compounds

Autor:	V. G. Vinogradova, Z. K. Maizus, L. D. Tyutchenkova
Rok vydání:	1978
Předmět:	Paramagnetism chemistry.chemical_compound Olefin fiber Chemistry Polymer chemistry chemistry.chemical_element General Chemistry Triphenylphosphine Photochemistry Oxygen Redox Isomerization Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:666-670
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925280
Popis:	1. Paramagnetic Rh(II)O2− and Rh(II)RO2complexes of similar structure are formed in solutions containing triphenylphosphine Rh(I) complexes, both in the presence of O2 and in the presence of a hydroperoxide in an oxygen-free medium. 2. Addition of a hydroperoxide promotes coordination of the Rh(I) compound with both oxygen and RO2.. 3. The Rh(II)RO2 complexes coordinate olefins. 4. The effectiveness of the hydroperoxides in oxidational olefin isomerization can be correlated with the ability to oxidize Rh(I) to Rh(II).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6c6e79702f603ed0f88baf9188b72ac7 https://doi.org/10.1007/bf00925280 Zobrazit plný text záznamu Full text from SpringerLink