Excess thermodynamic properties and FTIR studies of binary of 1, 3-dichlorobenzene with alkyl acetates (C1–C5) at different temperatures
| Autor: | V. Pandiyan, R. Gerald Arokiaraj, R. Raju, S. Ravikumar, K. Sivakumar, S. Karlapudi |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Materials science 010405 organic chemistry Methyl acetate Analytical chemistry Ethyl acetate General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Propyl acetate Dichlorobenzene chemistry.chemical_compound Molar volume chemistry Speed of sound Butyl acetate Alkyl |
| Zdroj: | Chemical Data Collections. 29:100504 |
| ISSN: | 2405-8300 |
| Popis: | Densities (ρ) and speed of sound (u) have been reported for the binary mixtures containing 1, 3- dichlorobenzene (1, 3-DCB) with methyl acetate, ethyl acetate, propyl acetate, butyl acetate and pentyl acetate at four different temperatures (T = 303.15, 308.15, 313.15 and 318.15 K) and at atmospheric pressure. The experimental data of densities and speeds of sound has been further utilized to calculate excess molar volume ( V m E ) and excess isentropic compressibility ( κ S E ) the excess properties have been fitted to Redlich-Kister equation. Further, V m E results have also been discussed by using Prigogine–Flory–Patterson (PFP). The experimental speeds of sound data in the present investigated mixtures were compared with various theoretical models like collision factor theory (CFT) and free length theory (FLT) to check their relative merits of pure component properties. Moreover, the experimental excess functions were correlated in terms of FTIR spectral analysis. |
| Databáze: | OpenAIRE |
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