Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization

Autor:	Arpan Das, Jasimuddin Ahmed, Soumi Chakraborty, Sayani Barman, Swadhin K. Mandal
Rok vydání:	2020
Předmět:	Primary (chemistry) Ligand Chemistry Reactive intermediate Metals and Alloys General Chemistry Combinatorial chemistry Redox Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Formylation Materials Chemistry Ceramics and Composites Surface modification
Zdroj:	Chemical Communications. 56:13788-13791
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d0cc05348a
Popis:	Herein, we report the synthesis of a Cr(III)-complex bearing a redox non-innocent phenalenyl-based ligand and its use as a catalyst for SET mediated hydrosilylative reduction of carbon dioxide towards formylation of primary amides under mild conditions. A preliminary mechanistic picture for this transformation has been proposed by isolation and characterization of several reactive intermediates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6c34ae1d88cb84447aba9f15cd82227c https://doi.org/10.1039/d0cc05348a Zobrazit plný text záznamu