Hydrothermal Synthesis of Porous Al2O3/Al Metal Ceramics: IV. Synthesis of Composite Porous Ceramics in the Presence of Microporous and Mesoporous Adsorbents

Autor: Zh. V. Krupen'kina, V. E. Romanenkov, A. I. Rat'ko, E. V. Bolotnikova
Rok vydání: 2004
Předmět:
Zdroj: Kinetics and Catalysis. 45:279-287
ISSN: 0023-1584
DOI: 10.1023/b:kica.0000023804.36126.e6
Popis: The formation of the structure and properties of mesoporous composite ceramics based on an ASD-1 aluminum powder and commercial adsorbent powders (zeolites and active alumina) was studied. It was found that the mechanism of the formation of contacts between the particles of commercial adsorbents and aluminum is analogous to the mechanism of synthesis of an Al(OH)3/Al composite. The dissolution of aluminum and the precipitation of the hydroxo complexes of aluminum from solution to the region of interparticle contacts are responsible for this mechanism. The resulting composite ceramics exhibited a polydisperse pore structure and high values of mechanical strength, gas permeability, and thermal conductivity; it can be used as a block adsorbent and catalyst support.
Databáze: OpenAIRE