ChemInform Abstract: The Reactions of Copper-Dibromodifluoromethane-Amide Systems with Alcohols

Autor:	Robert John Blade, James H. Clark, Martin A. McClinton
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Amide Substrate (chemistry) chemistry.chemical_element Organic chemistry Chelation Dibromodifluoromethane General Medicine Reaction system Copper
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199331137
Popis:	1,1,1-Trifluoro-2-arylethanes can be prepared by the trifluoromethyldehydroxylation of benzyl alcohols using the copper-dibromodifluoromethane-amide reaction system, although the yields are low. The mechanism of the reaction may involve chelation of the substrate to copper so that α-substituted benzyl alcohols and most other alcohols are unreactive.
Databáze:	OpenAIRE
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