Reactions of cyclopentadienylcopper(I) tributylphosphine with iodobenzenes

Autor:	Robert Wahren
Rok vydání:	1973
Předmět:	Inorganic Chemistry chemistry.chemical_compound Iodobenzenes chemistry Acetyl chloride Organic Chemistry Iodobenzene Materials Chemistry Tributylphosphine Physical and Theoretical Chemistry Photochemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 57:415-422
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)86622-x
Popis:	Cyclopentadienylcopper(I) tributylphosphine reacts with iodobenzenes to give arylcyclopentadienes. If the iodobenzene has strongly electron-attracting substituents, copper—iodine exchange may occur simultaneously. The resulting transient arylcopper compounds have been trapped with acetyl chloride but may otherwise give symmetric biphenyls.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6bec45293739f7a9a054fae26541ff5c https://doi.org/10.1016/s0022-328x(00)86622-x Zobrazit plný text záznamu